
In this Review, we highlight electrolyte design strategies to form LiF-rich interphases in different battery systems.. In this Review, we highlight electrolyte design strategies to form LiF-rich interphases in different battery systems.. Lithium-ion batteries (LIBs) have nowadays become outstanding rechargeable energy storage devices with rapidly expanding fields of applications due to convenient features like high energy density, high power density, long life cycle and not having memory effect.. This work provides insights into the design of low-temperature electrolytes with a wide electrochemical window, advancing the development of batteries for extreme conditions.. For practical applications, ensuring both the reversibility of the Li metal anode and electrolyte stability at high voltages is crucial. In this review, we explore recent advancements in addressing these challenges through new designs of electrolytes and SEI engineering practices.. Central to the structure of lithium batteries are the anode, cathode, separator, and electrolyte, with the latter serving as a critical determinant of both the capacity and performance of lithium secondary and primary batteries. [pdf]
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